Brown pork chops in a hot skillet sprayed with cooking spray-- approximately two minutes per side. Transfer the pork to a large casserole dish.
Spray the same skillet with cooking spray, add the peppers and onions, and cook until tender. Add all the remaining ingredients and cook, stirring often, for about five minutes or until heated through.
Pour the corn/tomato mixture from the skillet over the pork chops.
Cover with foil, and bake for 45-50 minutes or until pork is cooked through.