Preheat oven to 400 degrees. Combine the garlic, ginger, soy sauce, chile flakes, molasses, maple syrup, wine and sesame seeds in a large bowl. Add the chicken chicken and thoroughly in the soy mixture. Allow to marinate briefly while you prepare the broccoli.
Chop broccoli into 1 by 2 Inch florets. In a large bowl, toss in enough vegetable oil to coat. Salt to taste and spread out on a baking sheet.
Using tongs to leave the marinade behind, spread the chicken on a foil lined pan. Place chicken in the oven and bake for 12-15 minutes or until browned on the bottom. Add broccoli pan to oven, turning after 12 minutes and coking until tender. Cook the chicken an additional 12-15 minutes or until thick parts are throughly cooked.
Sprinkle the chicken with the cilantro and serve the broccoli over rice.